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Goce Delcev University-Stip, Krste Misirkov bb, Stip, Macedonia

Професор д-р Рубин Гулабоски/Prof. Dr Rubin Gulaboski

Prof. Dr Rubin Gulaboski (Dr.rer.nat.), Professor of Chemistry and Biochemistry

Faculty of Medical Sciences, Goce Delcev University, Krste Misirkov bb, 2000 Stip, Macedonia

http://www.rubingulaboski.synthasite.com

Email: rubin.gulaboski@ugd.edu.mk

Research   interest:  

Theoretical and Experimental Electrochemistry, Protein-film Voltammetry,   Redox Chemistry of Coenzyme Q10-like compounds, Electrochemical Impedance   Spectroscopy (EIS), Transfer of ionizable drugs across biomimetic membranes,   Synthesis of new vitamins and antioxidants, Theoretical modelling under   voltammetric conditions, Electrochemical features of nano-particles.

                                                                        

 Scientific Vita

Since 2009     

Associate professor of Chemistry and Biochemistry at the “Goce Delcev”   University-Stip,Macedonia

2008-2009

Post-doctorand (Humboldtian) and Scientific Researcher at the Faculty   of Medicine,SaarlandUniversity,Homburg,   Germany

2004-2008

Post-doctorand and Scientific Researcher at the Department of Chemistry,   Faculty of Natural Sciences, University of Porto, Porto, Portugal

2011-

Designated Associate professor (outdoor member) at the Institute of   Chemistry, Faculty of Natural Sciences and Mathematics, Ss “Cyril and   Methodius” University, Skopje, Macedonia

2001-2004

PhD student at the Department of Analytical Chemistry and   Biochemistry,Ernst-Moritz-ArndtUniversity,Greifswald,   Germany

1998-2001

MSCi at theInstituteofChemistry, Faculty of Natural Sciences and Mathematics,   Ss “Cyril and Methodius” University,Skopje,   Macedonia

1992-1997

Undergraduate studies of chemistry at theInstitute  ofChemistry, Faculty of Natural   Sciences and Mathematics, Ss “Cyril and Methodius” University,Skopje,Macedonia

Other activities and membership:

  • Referee Reviewer of more than 400 papers submitted for publication in more than 60 international peer journals
  • Active Participation in more than 20 national and international scientific projects
  • Invited Evaluator for scientific projects of the Ministry of Science and Education of Argentina
  • Invited Evaluator for scientific projects from Division for Chemical Sciences (CW) of the Netherlands Organisation for Scientific Research (NWO), The Netherlands.
  • Member of the Editorial Board of The Open Electrochemistry Journal, Macedonian Journal of Chemistry and Chemical Engineering, and International Journal of Electrochemistry.
  • According to SCOPUS and Google Scholar, the works of prof. Rubin Gulaboski are cited more than 1350 times. With this score he is one of 5 most cited authors from Macedonia from all fields.

Awards:

  • PhD scholarship of DAAD (A/01/11814) in the period 2001-2004
    • Post. Doc. Fellowship of Fundacao para a Ciencia e a Tecnologia (FCT- SFRH/BPD/14894/2004), Portugal, in the period 2004-2008
  • Alexander Von HUMBOLDT Postdoctoral Research Fellowship-2008/2009,Germany
  • Alexander von Humboldt Return Fellowship from 2009 to 2010
    • Award for one of 10 best young scientists at the EMLG/JMLG Annual Meeting “Liquid Systems under Extreme Conditions”,Barcelona3-7 September 2006
    •  "3rd November Award" the Highest Award of Municipality of Prilep,Macedonia, November 2009
    • Alexander von Humboldt-Special Award in Donation of Electrochemical Instrumentation-Potentiostat PGSTAT 128N, 2010.

Patent:

Gulaboski, R.; Bogeski, I.; Kappl, R.; Hoth, M.Benzoquinone based Antioxidants, European Patent Office, Munich 2011

Books

[1]        Scholz, F.; Schroeder, U.; Gulaboski, R. Electrochemistry of immobiliyed particles and droplets, Springer Verlag New Zork 2005, pp. 1-269

2. R. Gulaboski in Electrochemical Dictionary, A. J. Bard, G. Inzelt, F. Scholz (Eds) 2008 and 2nd Edition in 2012

3. Gulaboski R, Pereira, C. M. Electrochemical Methods and Instrumentation in Food Analysis, in Handbook of Food Analysis Instruments, S. Otles (Ed), Taylor and Francis 2008

Most relevant publications (all published in international journals with Impact Factor)

  1. R. Gulaboski, I. Bogeski, V. Mirceski, S. Mitrev et al. Hydroxilated derivatives of dimethoxy-1,4-benzoquinone as redox-switchable earth-alkaline metal ligands and radical scavangers, Nature Scientific Reports (2013)  DOI: 10.1038/srep01865 http://www.nature.com/srep/2013/130521/srep01865/pdf/srep01865.pdf
  2. R. Gulaboski, M. Lovric, V. Mirceski, I. Bogeski, M. Hoth, Protein-film voltammetry: a theoretical study of the temperature effect using square-wave voltammetry., Biophys. Chem. 137 (2008) 49-55.
  3. R. Gulaboski, Surface ECE mechanism in protein film voltammetry—a theoretical study under conditions of square-wave voltammetry, J. Solid State Electrochem. 13 (2009) 1015-1024
  4. R. Gulaboski, E. S. Ferreira, C. M. Pereira, M. N. D. S. Cordeiro, A. Garrau, V. Lippolis, A. F. Silva, Coupling of Cyclic Voltammetry and Electrochemical Impedance Spectroscopy for Probing the Thermodynamics of Facilitated Ion Transfer Reactions Exhibiting Chemical Kinetic Hindrances, J. Phys. Chem. C 112 (2008) 153-161.
  5. R. Gulaboski, C. M. Pereira, M. N. D. S. Cordeiro, M. Hoth, I. Bogeski, Redox properties of the calcium chelator Fura-2 in mimetic biomembranes. Cell Calcium 43 (2008) 615-621.
  6. R. Gulaboski, M. Chirea, C. M. Pereira, M. N. D. S. Cordeiro, R. B. Costa, A. F. Silva, Probing of the Voltammetric Features of Graphite Electrodes Modified with Mercaptoundecanoic Acid Stabilized Gold Nanoparticles, J. Phys. Chem. C 112 (2008) .2428-2435
  7. V. Mirceski, R. Gulaboski, I. Bogeski, M. Hoth, Redox Chemistry of Ca-Transporter 2-Palmitoylhydroquinone in an Artificial Thin Organic Film Membrane, J. Phys. Chem C 111 (2007) 6068-6076.
  8. R. Gulaboski, F. Borges, C. M. Pereira, M. N. D. S. Cordeiro, J. Garrido, A. F. Silva, Voltammetric insights in the transfer of ionizable drugs across biomimetic membranes: recent achievements., Combinatorial Chemistry&High Throughput Screening, 10 (2007) 514-526.
  9. R. Gulaboski, V. Mirčeski, M. Lovrić, I Bogeski, “Theoretical study of a surface electrode reaction preceded by a homogeneous chemical reaction under conditions of square-wave voltammetry.” Electrochem. Commun. 7 (2005) 515-522.
  10. Rubin Gulaboski, M. Natalia D.S. Cordeiro, Nuno Milhazes, Jorge Garrido, Fernanda Borges, Miguel Jorge, Carlos M. Pereira, Ivan Bogeski, Aluska Helguera Morales, Blaze Naumoski and A. Fernando Silva, “Evaluation of the lipophilic properties of opioids, amphetamine-like drugs, and metabolites through electrochemical studies at the interface between two immiscible solutions. Anal. Biochem. 361 (2007) 236-243.
  11. M. Jorge, R. Gulaboski, C. M. Pereira, M. N. D. S. Cordeiro, Molecular dynamics study of nitrobenzene and 2-nitrophenyloctyl ether saturated with water", Molecular Physics 104 (2006) 3627-3634.
  12. M. Jorge, R. Gulaboski, C. M. Pereira, M. N. D. S. Cordeiro “Molecular dynamics study of 2-nitrophenyl octyl ether and nitrobenzene.” J. Phys. Chem B 110 (2006) 12530-12538.
  13. Chirea M, Garcia-Morales V, Manzanares JA, Pereira C, Gulaboski R, Silva F, “Electrochemical characterization of polyelectrolyte/gold nanoparticle multilayers self-assembled on gold electrodes.” J. Phys. Chem B 109 (2005) 21808-21817.
  14. V. Mirčeski, R. Gulaboski, “Simple electrochemical method for deposition and voltammetric inspection of silver particles at the liquid-liquid interface of a thin-film electrode.” J. Phys. Chem B 110 (2006) 2812-2820.
  15. Rubin Gulaboski, Valentin Mirčeski, Carlos M. Pereira, M. Natalia D. S. Cordeiro, A. Fernando Silva, François Quentel, Maurice L’Her, Milivoj Lovrić, “A comparative study of the anion transfer kinetics across a water/nitrobenzene interface by means of electrochemical impedance spectroscopy and square-wave voltammetry at thin organic film-modified electrodes.” Langmuir 22 (2006) 3404-3412.
  16. R. Gulaboski, C. M. Pereira. M. N. D. S. Cordeiro, I. Bogeski, E. Fereira, D. Ribeiro, M. Chirea, A. F. Silva, “Electrochemical study of ion transfer of acetylcholine across the interface of water and a lipid-modified 1,2-dichloroethane.” J. Phys. Chem B 109 (2005) 12549-12559.
  17. R. Gulaboski, C. M. Pereira. M. N. D. S. Cordeiro, I. Bogeski, A. F. Silva “Enzymatic formation of ions and their detection at a three-phase electrode” J. Solid State Electrochem. 9 (2005) 469-474.
  18. F. Scholz, R. Gulaboski “Determining the Gibbs energy of ion transfer across water-organic liquid interfaces with three-phase electrodes.” Chem. Phys. Chem., 6 (2005) 1-13.
  19. F. Scholz, R. Gulaboski “Gibbs energies of transfer of chiral anions across the interface water/chiral organic solvent determined with the help of three-phase electrodes.” Faraday Discussion, 129 (2005) 169-177.
  20. R. Gulaboski, A. Galland, G. Bouchard, K. Caban, A. Kretschmer, P.–A. Carrupt, H. H. Girault, F. Scholz, A Comparison of the Solvation Properties of 2-Nitrophenyloctyl Ether, Nitrobenzene, and n-Octanol as Assessed by Ion Transfer Experiments” J. Phys. Chem. B. 108 (2004) 4565-4572.
  21. R. Gulaboski, F. Scholz, “Lipophilicity of Peptide Anions: An Experimental Data Set for Lipophilicity Calculations”,J. Phys. Chem. B. 107 (2003) 5650-5657.
  22. R. Gulaboski, K. Caban, Z. Stojek, F. Scholz, “The determination of the standard Gibbs energies of ion transfer between water and heavy water by using the three-phase electrode approach”, Electrochem. Commun. 6 (2004) 215-218.
  23. V. Mirčeski, R. Gulaboski, F. Scholz, “Square-wave thin-film voltammetry: influence of uncompensated resistance and charge transfer kinetics”, J. Electroanal. Chem. 566 (2004) 351-360.
  24. F. Scholz, R. Gulaboski, K. Caban, “The determination of standard Gibbs energies of transfer of cations across the nitrobenzene|water interface using a three-phase electrode.”, Electrochem. Commun., 5 (2003) 929-934.
  25. G. Bouchard, A. Galland, P.-A. Carrupt, R. Gulaboski, V. Mirčeski, F. Scholz, H. Girault, “Standard partition coefficients of anionic drugs in the n-octanol/water system determined by voltammetry at three-phase electrodes”, Phys. Chem. Chem. Phys. 5 (2003) 3748-3751.
  26. R. Gulaboski, V. Mirčeski, Š. Komorsky-Lovrić, M. Lovrić, “Square-Wave Voltammetry of Cathodic Stipping Reactions. Diagnostic Criteria, Redox Kinetic Measurements, and Analytical Applications”, Electroanalysis, 16(2004) 832-842. www3.interscience.wiley.com/journal/107641775/abstract
  27. V. Mirčeski, R. Gulaboski, “A Theoretical and Experimental Study of Two-Step Quasireversible Surface Reaction by Square-Wave Voltammetry” Croatica Chem. Acta 76 (2003) 37-48. http://public.carnet.hr/ccacaa/CCA-PDF/cca2003/v76-n1/CCA_76_2003_037-048_mirceski.pdf
  28. V. Mirčeski, R. Gulaboski, “The surface catalytic mechanism: a comparative study with square-wave and staircase cyclic voltammetry ”, J. Solid State Electrochem. 7 (2003) 157-165.
  29. R. Gulaboski, V. Mirčeski, Š. Komorsky-Lovrić, “Square-Wave Voltammetry of a Second Order Cathodic Stripping Process Coupled by Adsorption of the Reacting Ligand”, Electroanalysis, 14 (2002) 345-354.www3.interscience.wiley.com/journal/91512847/abstract
  30. V. Mirčeski, R. Gulaboski, “Adsorptive Stripping Voltammetric Behavior of Probucole. Experimental and Theoretical Treatment ”, Mikrochim. Acta, 138 (2002) 33.
  31. V. Mirčeski, M. Lovrić, R. Gulaboski, “Theoretical and experimental study of the surface redox reaction involving interactions between the adsorbed particles.under conditions of square-wave voltammetry.”, J. Electroanal. Chem.,515 (2001) 91-99.
  32. R. Gulaboski, I. Spirevska, L. Soptrajanova, R. Slavevska, “SQUARE-WAVE VOLTAMMETRIC METHOD FOR DETERMINATION OF FUMARIC AND MALEIC ACID—DETERMINATION OF FUMARIC ACID IN WINE”, Anal. Letters, 34 (2001) 1719-1731.
  33. Valentin Mirčeski, Rubin Gulaboski, “Surface Catalytic Mechanism in Square-Wave Voltammetry”,Electroanalysis, 13 (2001) 1326-1334. www3.interscience.wiley.com/journal/88010632/abstract
  34. Rubin Gulaboski, Kay Riedel, and Fritz Scholz, “Standard Gibbs energies of transfer of halogenate and pseudohalogenate ions, halogen substituted acetates, and cycloalkyl carboxylate anions at the water|nitrobenzene interface”, Phys. Chem. Chem. Phys. 5 (2003) 1284-1289.
  35. Rubin Gulaboski, Valentin Mirčeski and Fritz Scholz, “Determination of the standard Gibbs energies of transfer of cations and anions of amino acids and small peptides across the water nitrobenzene interface.”, Amino Acids, 24(2003) 149-154
  36. F. Scholz, R. Gulaboski, V. Mirčeski, P. Langer, „Quantification of the chiral recognition in electrochemically driven ion transfer across the interface water/chiral liquid.” Electrochem. Commun., 4 (2002) 659-662.
  37. Valentin Mirčeski, Rubin Gulaboski and Fritz Scholz, “Determination of the standard Gibbs energies of transfer of cations across the nitrobenzene|water interface utilizing te reduction of Iodine in an immobilized dropplett“Electrochem. Commun., 4 (2002) 814-819.
  38. Šebojka Komorsky-Lovrić, Kay Riedl, Rubin Gulaboski, Valentin Mirčeski and Fritz Scholz, “Determination of Standard Gibbs Energies of Transfer of Organic Anions across the Water/Nitrobenzene Interface” Langmuir, 18(2002), 8000-8005.
  39. Rubin Gulaboski, Valentin Mirčeski and Fritz Scholz, “An An electrochemical method for determination of the standard Gibbs energy of anion transfer between water and n-octanol” Electrochem. Commun., 4 (2002) 277-283.
  40. Valentin Mirčeski, Rubin Gulaboski and Igor Kuzmanovski, “Mathcad-a Tool for Numerical Calculation of Square-Wave Voltammograms”, Bull. Chem. Technol. Macedonia, 18 (1999) 57-64.
    www.pmf.ukim.edu.mk/PMF/Chemistry/members/kuzmi/1999_BullChemTechMac
  41. Kornelija Stojanova, Rubin Gulaboski, Valentin Mirčeski and Simka Petrovska-Jovanović, “Adsorptive Stripping Square-Wave Voltammetry of Creatine”, Anal. Letters, 32 (2000) 2937-2950.
  42. Ilinka Spirevska, Lidija Soptrajanova, Rubin Gulaboski, “Square-Wave Voltammetric Method for Determination of Aconitic Acid”, Anal. Letters, 33 (2000) 919-928.

43.Blagoja Jordanoski, Valentin Mirčeski, Rubin Gulaboski, „Square-Wave Voltammetric Determination of Sulpiride“,Portugal. Electrochim. Acta, 17 (1999) 243-253.

44. Valentin Mirčeski, Rubin Gulaboski, Blagoja Jordanoski and Šebojka Komorsky-Lovrić, „Square-wave voltammetry of 5-fluorouracil “, J. Electroanal. Chem., 490 (2000) 37-47

45. Valentin Mirčeski, Rubin Gulaboski, Simka Petrovska-Jovanović, Kornelija Stojanova, „Characterization of the Redox Reaction of V(V) in Ammonia Buffers with Square-Wave Voltammetry“, Portugal. Electrochim. Acta, 19 (2001) 25-41.

46. Ivan Bogeski, Rubin Gulaboski*, Reinhard Kappl, Valentin Mirceski, Marina Stefova, Jasmina Petreska, Markus Hoth, „Calcium Binding and Transport by Coenzyme Q„ Journal of the American Chemical Society 133 (2011) 9293-9303  http://pubs.acs.org/doi/abs/10.1021/ja110190t 

47. R. Gulaboski, I. Bogeski, V. Mirceski, S. Mitrev et al.  Nature Scientific Reports 2013

48. Rubin Gulaboski, Blagoja Jordanoski, “Square-Wave Voltammetry of Ofloxacin”, Bull. Chem. Technol. Macedonia,19 (2000) 177-181. http://www.mjcce.org.mk/PDF/19_2_178.pdf

49. Rubin Gulaboski, Ilinka Spirevska, Lidija Soptrajanova, "Square-wave voltammetric method developed for determination of geometrical isomers citraconic and mesaconic acids, Bulletin of the Macedonian Academy of Sciences, 2003.

50. Rubin Gulaboski, “Theoretical and experimental treatment of the redox processes coupled by adsorption phenomena under conditions of Square-wave voltammetry” Master Thesis, 2001.

51. Rubin Gulaboski “The Determination of the Standard Gibbs Energies of Ion Transfer across the Liquid|Liquid Interfaces with the Help of Three-Phase Electrodes”, PhD Thesis, Greifswald, June 2004.

52.V. Mirceski, S. Hocevar, B. Ogorevc, R. Gulaboski, I. Drangov, "Diagnostics of Anodic Stripping Mechanisms under Square-Wave Voltammetry Conditions Using Bismuth Film Substrates" Analytical Chemistry 84 (2012)  4429-4436 http://pubs.acs.org/doi/abs/10.1021/ac300135x

53.R. Gulaboski, P. Kokoskarova, S. Mitrev, "Theoretical aspects of several successive two-step redox mechanisms in protein-film cyclic staircase voltammetry" Electrochimica  Acta 69 (2012) 86-96.http://www.sciencedirect.com/science/article/pii/S001346861200300349.

 54.R. Gulaboski, M. Lovric, V. Mirceski, I. Bogeski, M. Hoth, A new rapid and simple method to determine the kinetics of electrode reactions of biologically relevant compounds from the half-peak width of the square-wave voltammograms.,Biophys. Chem. 138 (2008) 130-137.

55. Rubin Gulaboski, Ljupco Mihajlov, "Catalytic mechanism in successive two-step protein-film voltammetry—Theoretical study in square-wave voltammetry", Biophysical Chemistry 155 (2011) 1-9.

56. Rubin Gulaboski, Valentin Mirceski, Ivan Bogeski, Markus Hoth, „Protein film voltammetry: electrochemical enzymatic spectroscopy. A review on recent progress„ Journal of Solid State Electrochemistry (2011) in press.http://www.springerlink.com/content/fq93369v88507446/

57. Ivan Bogeski, Rubin Gulaboski*, Reinhard Kappl, Valentin Mirceski, Marina Stefova, Jasmina Petreska, Markus Hoth, „Calcium Binding and Transport by Coenzyme Q„ Journal of the American Chemical Society 133 (2011) 9293-9303 http://pubs.acs.org/doi/abs/10.1021/ja110190t

58.B. Sefer, R. Gulaboski,V. Mirceski, Electrochemical deposition of gold at liquid–liquid interfaces studied by thin organic film-modified electrodes, J. Solid State Electrochem 16 (2012) 2373-2381.http://www.springerlink.com/content/158616378232321g/

59.Rubin Gulaboski, Valentin Mirceski, Ivan Bogeski, Markus Hoth, „Protein film voltammetry: electrochemical enzymatic spectroscopy. A review on recent progress„ Journal of Solid State Electrochemistry 16 (2012) 2315-2328.  http://www.springerlink.com/content/fq93369v88507446/

60.R. Gulaboski. V. Mirceski, S. Mitrev, Development of a rapid and simple voltammetric method to determine the total antioxidative capacity of edible oils, Food Chemistry 138 (2013) 116-121 doi 10.1016/j.foodchem.2012.10.050  http://0-www.sciencedirect.com.precise.petronas.com.my/science/article/pii/S0308814612015889?v=s5

61. Ivan Bogeski, Reinhard Kappl, Carsten Kumerow, Rubin Gulaboski, Markus Hoth, Barbara A. Niemeyer "Redox regulation of calcium ion channels: Chemical and physiological aspects, Cell Calcium 50 (2011) 407-423.http://www.sciencedirect.com/science/article/pii/S0143416011001503.

62. Liljana Koleva-Gudeva, Rubin Gulaboski, Emilija Janevic-Ivanovska, Fidanka trajkova, Viktorija Maksimova, Capsaicin-Inhibitory Factor for Somatic Emrbyogenesis in pepper Anther Culture, Electronic Journal of Biology, 9 (2013) 29-36